How to Disconnect a PS5 Controller from a PC
You can also hold the PlayStation button and the Create button on the controller simultaneously until the light bar starts flashing to reset it. It’ll unpair from the PC!
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Easy peasy! Just go to your Bluetooth settings on your PC, find the PS5 controller in the list of paired devices, and click 'Remove device.'
Just turn off the Bluetooth on your PC. It'll disconnect the controller instantly.
Plug in the controller to your PS5 using the USB cable, and it should reconnect to the console, disconnecting it from the PC in the process. Worked for me!
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