How to exit fullscreen on Steam
Press 'F11' to quickly exit fullscreen mode while you're navigating in the Steam browser or playing a game that supports this shortcut. If that doesn't work, try looking for an 'exit fullscreen' option in the game's settings menu – usually found under 'video' or 'display' settings.
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Just Alt+Tab out of the game. Works like a charm for me every time when I'm stuck in fullscreen and need to check something else on my desktop.
Honestly, just hitting ESC usually does the trick for me. Quick and easy.
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