How to Unsync an Xbox One Controller
To unsync the controller, go to Settings > Devices & Accessories, select the controller, and choose the option to 'Turn off' the controller. Easy peasy!
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Just restart your Xbox One console. The controller will become unsynced automatically.
Just press and hold the sync button on the console for about 10 seconds until the light on the controller turns off.
Best way I found is to press and hold the Xbox button on the controller until it turns off. Works like a charm!
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